The released air
bubbles become attached to the suspended particles by one of the following
mechanisms:
- Condensation
- Collision
- Entrapment
In the condensation
mechanism, air in excess of atmospheric saturation comes out of solution
by formation on the surface of the suspended particle. This is not the
dominant mechanism, however, since non-turbulent depressurization of the
suspension results in a degree of super saturation. Hence, it is necessary
to first achieve near complete air release by turbulence before attachment
to the particles.
The collision mechanism is
perhaps the most significant in the flotation process. In this mechanism,
the air-to-solids bond is created by collision during random motion. Air
bubble and particle size must be controlled to some extent to ensure that
there is a sufficient radius of attachment to maintain the bond until
separation. Particle size is controlled by the amount of chemical added
during the enflocculation process.
The entrapment mechanism,
which provides a "permanent" air-to-solids bond, can be the
predominant mechanism when the final step of chemical flocculation occurs
after air release. This occurs as the air bubbles become embedded in the
floc mass.
After the air-to-solids bond is complete,
flotation will occur if the net combined specific gravity of the
air-to-solids agglomerate is less than 1.0. Rise rate of the undisturbed
agglomerate is governed by Stokes' Law. The revised Stokes' Equation for
the flotation process is:
Vt
= (p liquid - pa) Da2
u
18
In
this formula Vt = terminal velocity agglomerate, p = density of liquid, pa
= density of agglomerate, u = viscosity of the liquid, and g =
acceleration due to gravity.
Actual
separation of the suspension in the flotation unit will also be governed
by the solids and air concentration; and, the degree of turbulence.
The
flotation process is employed where separation of particles having
specific gravities close to that of water is desired. The flotation
process will provide faster separation and higher ultimate solids
concentration. Sludge volume generated by the DAF process will be nearly
equal to other system processes, but the DAF will have more air volume
entrapped with the sludge; therefore, less water entrapment.
Equipment
Used in the Flotation Process
The
DAF unit consists of two major components: the retention tank and the
separation vat. The retention tank is a pressure vessel designed to
provide sufficient time for dissolution of air into the stream to be
treated. There are a variety of air introduction systems available, most
employing a sparger or ductor.
From
the retention tank, the stream is released back to atmospheric pressure in
the separation vat. The system is usually designed so that most of the
pressure drop occurs in the transfer line between the retention tank and
the separation vat so that the effects of turbulence are minimized. In the
separation vat, air in excess of atmospheric saturation comes out of
solution in the form of tiny air bubbles, which become attached to the
particles in the suspension, thus resulting in floating of the particles.
The separation vat is equipped with a flight scraper mechanism, which
removes the floated material to a recovered solid compartment. Clarified
effluent is drawn off from the bottom of the vat. There are a number of
different vat configurations and process application methods available to
satisfy the conditions of a particular application.
There
are three general parameters involved in sizing DAF cells:
-
Hydraulic
Loading (gpm/ft2)
-
Solids
Loading (lbs/hours/ft2)
-
Air-to-Solids
Ratio (lbs of air/lbs of solids)
Generally,
one of the above parameters will be the controlling design point.
Hydraulic
Loading: The relationship of the surface area of the flotation
cell (ft2) versus the influent rate into the flotation cell (gpm).
For full pressurization systems, the influent rate is the capacity of the
pressurizing pumps. For recycle pressurization systems, the total influent
is the raw influent flow plus the recycle pump rate. Effective design
ranges are 1.0 to 2.5 gpm/ft2, depending upon the application.
Solids
Load: The relationship of the surface area of the flotation cell
(ft2) versus the amount of solids (lbs) entering the system per
hour. Design points for solid loadings range from 0.5 to 3.5 lbs/hr/ft2,
depending on the application and the type of solids involved. It should be
noted that any chemical additives used to promote coagulation and
flocculation are generally included as solids determining the surface
loading since the chemicals used are removed with the float from the
system.
Air-to-Solid
Ratio: The ratio of the number of pounds of air to the number of
pounds of solids. Generally, air is injected in a range of two percent to
eight percent (2% to 8%) by volume. Depending upon the type of solids and
application, the air-to-solids ratio ranges from 0.020 to 0.1.
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